Design and synthesis of stable α-diazo-β-oxo sulfoxides.
نویسندگان
چکیده
Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable α-diazo-β-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic α-diazo-β-oxo sulfoxides are too labile to isolate and characterize.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 11 10 شماره
صفحات -
تاریخ انتشار 2013